ABOUT STEEL


The type of steel used

The following is a qualitative account of some of the details of the steel used to construct the Sizewell 'B' reactor pressure vessel, and how such steel behaves under extreme stress levels. This account is based upon published accounts of work in the field across the world, and over the years. It is neither exhaustive nor definitive. But it is food for thought.

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Low Alloy Steel

The Sizewell 'B' reactor pressure vessel is made from "low alloy steel type A355B". Steel was invented in the nineteenth century by reducing and controlling the amount of carbon included within it. The strength of steel can be much increased by small additions of some other metals during manufacture.

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The Composition of A533b Low Alloy Steel

A533B steel has density 7.83 grams per cubic centimetre, and nominal composition:-
ingredientatoms percent
Iron 97.02
Nickel 0.52
Manganese 1.31
Carbon 1.15
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The effects of impurities and cold work

Some impurities present in steel can have adverse effects on the physical properties and need to be tightly controlled below maximum permissible values. These include hydrogen and copper. The effects of fusion welding, neutron irradiation, stress cycling, stress at high temperatures, and corrosion on steel are known to affect the composition and structure of steel adversely. Permanent deformation at low temperatures, known as 'cold work' also makes it harder and less ductile.

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Low Alloy Steel - the inside story

Iron melts around 1800 degrees centigrade and on solidification and cooling it has a system of allotropic forms. If the temperature is reduced very slowly to room temperature it is found to consist of tightly packed metallic grains each with a body centred cubic 'crystalline' structure, known as ferrite. When other elements are present the structure is more complicated. Carbon and iron tend to combine in different ways in different temperature ranges, and the changes involved in going from one stable form to another take time to occur, so that in addition to the chemical composition, the rate of temperature change is an important factor in determining the physical properties of the end product. For example rapid cooling from a temperature of 1000 degrees centigrade produces a hard brittle product with the structure which existed at the high temperature. This procedure is called quenching or hardening. Once in the hard state, the properties can be controlled by 'soaking' the steel at intermediate temperatures and subjecting it to cooling at carefully controlled rates of temperature reduction. The properties of the steel are measured by mechanical procedures which, because of the inhomogeneous nature of the product, give enormously variable results. For example, the shear strength of the steel can be calculated theoretically by reference to the known properties of the ferrite crystal atomic structure. However, the value measured in tests is only one thousandth of the theoretical value indicating the extent to which it is weakened by internal irregularities and disorder. The granular structure of the steel can be examined by the standard crystallographic polishing and etching techniques. Fusion welding thick steel sections together is achieved by filling a gap between the sections with 'passes' of deposited weld metal. For each 'pass' during which one strip of fusion weld metal is deposited, the adjacent parent metal is heated up to the melting point and down again. The Sizewell 'B' vessel cylindrical wall is 215 millimetres thick, necessitating about sixty passes to deposit the required amount of weld metal. The welding is performed in sequence from both the inside and the outside of the vessel, with the 'root' of the inside welds cut away before application of the outside weld. The parent steel in the vicinity of the weld is said to contain a 'heat affected zone', abbreviated to HAZ. The physical properties of the weld metal need to be controlled independently of the parent material in order to ensure so far as possible that failure of the weld does not occur preferentially. Uneven cooling of steel from high temperature causes variation in the crystal structure within the component. Local variations in density which result, mean that stress fields exist within the component which, if they remain in service, will modify the actual stress distribution in service from that assumed in the design procedure. It is not unusual for quite large cracks to form during poorly conducted temperature control.

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